Real-time dissociation dynamics of the Ne(2)Br(2) van der Waals complex.
نویسندگان
چکیده
We have characterized the vibrational predissociation (VP) of the Ne(2)Br(2) van der Waals complex using time- and frequency-resolved pump-probe spectroscopy. After exciting Br(2) within the complex to a vibrational level 1619. We also report vibrational product state distributions for direct excitation to NeBr(2) 16<or=nu(')<or=23. For NeBr(2), the dominant product channel is Br(2) (nu(')-1) for all initial nu(') studied, consistent with this complex dissociating primarily via direct VP.
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ورودعنوان ژورنال:
- The Journal of chemical physics
دوره 133 1 شماره
صفحات -
تاریخ انتشار 2010